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<?php

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_general/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_general/email');

#Sales Representative

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_sales/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_sales/email');
#Customer Support

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_support/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_support/email');
#Custom Email 1

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_custom1/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_custom1/email');
#Custom Email 2

 
/* Sender Name */
Mage::getStoreConfig('trans_email/ident_custom2/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_custom2/email');

Get Phone no
<?php echo Mage::getStoreConfig('general/store_information/phone');?>