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if (isset($_FILES['uploaded_file']) &&
    $_FILES['uploaded_file']['error'] == UPLOAD_ERR_OK) {
    $mail->AddAttachment($_FILES['uploaded_file']['tmp_name'],
                         $_FILES['uploaded_file']['name']);
}
//Basic example can also be found here.

//The function definition for AddAttachment is:

public function AddAttachment($path,
                              $name = '',
                              $encoding = 'base64',
                              $type = 'application/octet-stream')

<?php

require("class.phpmailer.php");

$mail = new PHPMailer();

$mail->IsSMTP();  // telling the class to use SMTP
$mail->Host     = "smtp.example.com"; // SMTP server

$mail->From     = "from@example.com";
$mail->AddAddress("myfriend@example.net");

$mail->Subject  = "First PHPMailer Message";
$mail->Body     = "Hi! \n\n This is my first e-mail sent through PHPMailer.";
$mail->WordWrap = 50;

if(!$mail->Send()) {
  echo 'Message was not sent.';
  echo 'Mailer error: ' . $mail->ErrorInfo;
} else {
  echo 'Message has been sent.';
}
?>