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<?php
$cannonieri = array(
    array(
        'goals' => 22,
        'nome' => 'Icardi',
        'squadra' => 'Inter'
    ),
    array(
        'goals' => 21,
        'nome' => 'Toni',
        'squadra' => 'Verona'
    ),
    array(
        'goals' => 20,
        'nome' => 'Tevez',
        'squadra' => 'Juve'
    )
);
 
$squadre = array_column($cannonieri, 'squadra');
print_r($squadre); 
echo "<br>";
$goals = array_column($cannonieri, 'squadra', 'goals');
print_r($goals);
?>