Вutton to the right and H3 to the left
<div class="pull-right" role="group">
<button type="button" class="btn btn-info">
<span class="glyphicon glyphicon-plus" aria-hidden="true"></span>
Пользователь
</button>
</div>
<div class="text-left">
<h3>Пользователи</h3>
</div>
<hr />