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Add-PsSnapin Microsoft.SharePoint.PowerShell
Set-location $home

$topSite = Get-SPSite http://portal.opwftg.com/sites/OPWSS
"" | Out-File "C:\temp\UsersRoles.txt"
foreach($s in $topSite.AllWebs)
{
    if($s.HasUniquePerm -eq "True")
    {
		if($s.URL -eq 'http://portal.opwftg.com/sites/OPWSS/Teams/OPCO/OES'){
            "Site URL:" + $s.URL
			"Site Title: " + $s.Title #| Out-File "C:\temp\UsersRoles.txt" -append
            "`n"
            "Site Groups"
            "*************************"
            #$s.Users #| Format-Table -Property UserLogin, DisplayName | Out-File "C:\temp\UsersRoles.txt" -append
            $s.RoleAssignments | Format-Table -AutoSize -Property Member, RoleDefinitionBindings | Out-File "C:\temp\UsersRoles.txt" -Append
			$groups = $s.Groups
			foreach ($grp in $groups) {"Group: " + $grp.name; foreach ($user in $grp.users) {"  User: " + $user.name} }
            "Users at the website level"
            "**************************"
            $s.Users
            foreach($u in $s.Users){
                $u.DisplayName
                $u.Roles
            }
            "`n"
            "Lists and Libraries with Unique Permissions"
            "*******************************************"
			foreach($l in $s.Lists)
            {
                if($l.HasUniqueRoleAssignments -eq $true)
                {
                    "*************************"
                    "List: " + $l.Title
                    "List Groups and individual Assignments"
                    "*************************"
                    ##$l.RoleAssignments
                    "Role Assignments:"
                    foreach($r in $l.RoleAssignments){
                        "Member Name: " + $r.Member.Name
                        foreach($role in $r.RoleDefinitionBindings){
                         "Role Name: " + $role.Name
                         
                        }
                        "`r"
                    }

                }
            }
		}
    }
}