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(function($){
    var random = 0;

    $.expr[':'].random = function(a, i, m, r) {
        if (i == 0) {
            random = Math.floor(Math.random() * r.length);
        }
        return i == random;
    };

})(jQuery);

// This is how you use it:
$('li:random').addClass('glow');